Record Efficiency of 18.7 Percent for Flexible Solar Cells on Plastics, Swiss Researchers Report

The measurements have been independently certified by the Fraunhofer Institute for Solar Energy Systems in Freiburg, Germany.

It's all about money. To make solar electricity affordable on a large scale, scientists and engineers worldwide have long been trying to develop a low-cost solar cell, which is highly efficient, easy to manufacture and has high throughput. Now a team at Empa's Laboratory for Thin Film and Photovoltaics, led by Ayodhya N. Tiwari, has made a major step forward."The new record value for flexible CIGS solar cells of 18.7% nearly closes the"efficiency gap" to solar cells based on polycrystalline silicon (Si) wafers or CIGS thin film cells on glass," says Tiwari. He is convinced that"flexible and lightweight CIGS solar cells with efficiencies comparable to the"best-in-class" will have excellent potential to bring about a paradigm shift and to enable low-cost solar electricity in the near future."

One major advantage of flexible high-performance CIGS solar cells is the potential to lower manufacturing costs through roll-to-roll processing while at the same time offering a much higher efficiency than the ones currently on the market. What's more, such lightweight and flexible solar modules offer additional cost benefits in terms of transportation, installation, structural frames for the modules etc., i.e. they significantly reduce the so-called"balance of system" costs. Taken together, the new CIGS polymer cells exhibit numerous advantages for applications such as facades, solar farms and portable electronics. With high-performance devices now within reach, the new results suggest that monolithically-interconnected flexible CIGS solar modules with efficiencies above 16% should be achievable with the recently developed processes and concepts.

At the forefront of efficiency improvements

In recent years, thin film photovoltaic technology based on glass substrates has gained sufficient maturity towards industrial production; flexible CIGS technology is, however, still an emerging field. The recent improvements in efficiency in research labs and pilot plants -- among others by Tiwari's group, first at ETH Zurich and since a couple of years now at Empa -- are contributing to performance improvements and to overcoming manufacturability barriers.

Working closely with scientists at FLISOM, a start-up company who is scaling up and commercializing the technology, the Empa team made significant progress in low-temperature growth of CIGS layers yielding flexible CIGS cells that are ever more efficient, up from a record value of 14.1% in 2005 to the new"high score" of 18.7% for any type of flexible solar cell grown on polymer or metal foil. The latest improvements in cell efficiency were made possible through a reduction in recombination losses by improving the structural properties of the CIGS layer and the proprietary low-temperature deposition process for growing the layers as well as in situ doping with Na during the final stage. With these results, polymer films have for the first time proven to be superior to metal foils as a carrier substrate for achieving highest efficiency.

Record efficiencies of up to 17.5% on steel foils covered with impurity diffusion barriers were so far achieved with CIGS growth processes at temperatures exceeding 550°C. However, when applied to steel foil without any diffusion barrier, the proprietary low temperature CIGS deposition process developed by Empa and FLISOM for polymer films easily matched the performance achieved with high-temperature procedure, resulting in an efficiency of 17.7%. The results suggest that commonly used barrier coatings for detrimental impurities on metal foils would not be required."Our results clearly show the advantages of the low-temperature CIGS deposition process for achieving highest efficiency flexible solar cells on polymer as well as metal foils," says Tiwari.

The projects were supported by the Swiss National Science Foundation (SNSF), the Commission for Technology and Innovation (CTI), the Swiss Federal Office of Energy (SFOE), EU Framework Programmes as well as by Swiss companies W.Blösch AG and FLISOM.

Scaling up production of flexible CIGS solar cells

The continuous improvement in energy conversion efficiencies of flexible CIGS solar cells is no small feat, says Empa Director Gian-Luca Bona."What we see here is the result of an in-depth understanding of the material properties of layers and interfaces combined with an innovative process development in a systematic manner. Next, we need to transfer these innovations to industry for large scale production of low-cost solar modules to take off." Empa scientists are currently working together with FLISOM to further develop manufacturing processes and to scale up production.

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Original Versus Copy: Researchers Develop Forgery-Proof Prototypes for Product Authentication

For this, all the data has to be electronically checked. In the framework of the"Crypta" project supported by the Federal Ministry for Transport, Innovation and Technology (BMVIT), scientists from Graz University of Technology have now developed a prototype which safeguards objects according to new standards.

Whether for checking the origin of foodstuffs or as proof of authenticity of drugs, the future will bring an increased use of electronic assistants to make sure that the quality is right. RFID (Radio Frequency Identification) technology enables objects to be identified wirelessly."You need a reading device and an RFID tag which communicate with each other," explains project leader Jörn-Marc Schmidt from the Institute of Applied Information Processing and Communications at Graz University of Technology. There is a difference between active and passive tags. The former are connected to a power source whereas the latter draw the required power directly from the field of the reading unit, which makes them particularly suitable, for instance, for applications in supermarkets.

Private Key

For a long time the same electronic keys were used for these energy-efficient passive tags and their readers -- using what experts call symmetrical methods."In asymmetrical methods, the transmitter and receiver possess different keys. Secure digital signatures are thus made possible," adds Jörn-Marc Schmidt. Together with the semiconductor manufacturer austriamicrosystems and RF-iT Solutions GmbH, an RFID software and services provider from Graz, the researchers have now developed a prototype which uses a standard method for passive tags for the first time.

"For every tag there is a public key and a private key which remains secret," explains Jörn-Marc Schmidt. This is a development which could be made use of everywhere where proof of authenticity is important. The research results are the gratifying outcome of the Crypta research project of the FIT-IT funding line of the BMVIT, which supports application-oriented research in information technology in particular.

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Forecast Calls for Nanoflowers to Help Return Eyesight: Physicist Leads Effort to Design Fractal Devices to Put in Eyes

These flowers are not roses, tulips or columbines. They will be nanoflowers seeded from nano-sized particles of metals that grow, or self assemble, in a natural process -- diffusion limited aggregation. They will be fractals that mimic and communicate efficiently with neurons.

Fractals are"a trademark building block of nature," Taylor says. Fractals are objects with irregular curves or shapes, of which any one component seen under magnification is also the same shape. In math, that property is self-similarity. Trees, clouds, rivers, galaxies, lungs and neurons are fractals, Taylor says. Today's commercial electronic chips are not fractals, he adds.

Eye surgeons would implant these fractal devices within the eyes of blind patients, providing interface circuitry that would collect light captured by the retina and guide it with almost 100 percent efficiency to neurons for relay to the optic nerve to process vision.

In an article titled"Vision of beauty" forPhysics World, Taylor, a physicist and director of the UO Materials Science Institute, describes his envisioned approach and how it might overcome the problems occurring with current efforts to insert photodiodes behind the eyes. Current chip technology is limited, because it doesn't allow sufficient connections with neurons.

"The wiring -- the neurons -- in the retina is fractal, but the chips are not fractal," Taylor says."They are just little squares of electrodes that provide too little overlap with the neurons."

Beginning this summer, Taylor's doctoral student Rick Montgomery will begin a yearlong collaboration with Simon Brown at the University of Canterbury in New Zealand to experiment with various metals to grow the fractal flowers on implantable chips.

The idea for the project emerged as Taylor was working under a Cottrell Scholar Award he received in 2003 from the Research Corporation for Science Advancement. His vision is now beginning to blossom under grants from the Office of Naval Research (ONR), the U.S. Air Force and the National Science Foundation.

Taylor's theoretical concept for fractal-based photodiodes also is the focus of a U.S. patent application filed by the UO's Office of Technology Transfer under Taylor's and Brown's names, the UO and University of Canterbury.

The project, he writes in thePhysics Worldarticle, is based on"the striking similarities between the eye and the digital camera." (Physics Worldarticle is available at:http://physicsworld.com/cws/article/indepth/45840)

"The front end of both systems," he writes,"consists of an adjustable aperture within a compound lens, and advances bring these similarities closer each year." Digital cameras, he adds, are approaching the capacity to capture the 127 megapixels of the human eye, but current chip-based implants, because of their interface, are only providing about 50 pixels of resolution.

Among the challenges, Taylor says, is determining which metals can best go into body without toxicity problems."We're right at the start of this amazing voyage," Taylor says."The ultimate thrill for me will be to go to a blind person and say, we're developing a chip that one day will help you see again. For me, that is very different from my previous research, where I've been looking at electronics to go into computers, to actually help somebody… if I can pull that off that will be a tremendous thrill for me."

Taylor also is working under a Research Corp. grant to pursue fractal-based solar cells.

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Electronic Life on the Edge: Scientists Discover the Edge States of Graphene Nanoribbons

A graphene nanoribbon is a strip of graphene that may be only a few nanometers wide (a nanometer is a billionth of a meter). Theorists have envisioned that nanoribbons, depending on their width and the angle at which they are cut, would have unique electronic, magnetic, and optical features, including band gaps like those in semiconductors, which sheet graphene doesn't have.

"Until now no one has been able to test theoretical predictions regarding nanoribbon edge-states, because no one could figure out how to see the atomic-scale structure at the edge of a well-ordered graphene nanoribbon and how, at the same time, to measure its electronic properties within nanometers of the edge," says Michael Crommie of Berkeley Lab's Materials Sciences Division (MSD) and UC Berkeley's Physics Division, who led the research."We were able to achieve this by studying specially made nanoribbons with a scanning tunneling microscope."

The team's research not only confirms theoretical predictions but opens the prospect of building quick-acting, energy-efficient nanoscale devices from graphene-nanoribbon switches, spin-valves, and detectors, based on either electron charge or electron spin. Farther down the road, graphene nanoribbon edge states open the possibility of devices with tunable giant magnetoresistance and other magnetic and optical effects.

Crommie and his colleagues have published their research inNature Physics, available May 8, 2011 in advanced online publication.

The well-tempered nanoribbon

"Making flakes and sheets of graphene has become commonplace," Crommie says,"but until now, nanoribbons produced by different techniques have exhibited, at best, a high degree of inhomogeneity" -- typically resulting in disordered ribbon structures with only short stretches of straight edges appearing at random. The essential first step in detecting nanoribbon edge states is access to uniform nanoribbons with straight edges, well-ordered on the atomic scale.

Hongjie Dai of Stanford University's Department of Chemistry and Laboratory for Advanced Materials, a member of the research team, solved this problem with a novel method of"unzipping" carbon nanotubes chemically. Graphene rolled into a cylinder makes a nanotube, and when nanotubes are unzipped in this way the slice runs straight down the length of the tube, leaving well-ordered, straight edges.

Graphene can be wrapped at almost any angle to make a nanotube. The way the nanotube is wrapped determines the pitch, or"chiral vector," of the nanoribbon edge when the tube is unzipped. A cut straight along the outer atoms of a row of hexagons produces a zigzag edge. A cut made at a 30-degree angle from a zigzag edge goes through the middle of the hexagons and yields scalloped edges, known as"armchair" edges. Between these two extremes are a variety of chiral vectors describing edges stepped on the nanoscale, in which, for example, after every few hexagons a zigzag segment is added at an angle.

These subtle differences in edge structure have been predicted to produce measurably different physical properties, which potentially could be exploited in new graphene applications. Steven Louie of UC Berkeley and Berkeley Lab's MSD was the research team's theorist; with the help of postdoc Oleg Yazyev, Louie calculated the expected outcomes, which were then tested against experiment.

Chenggang Tao of MSD and UCB led a team of graduate students in performing scanning tunneling microscopy (STM) of the nanoribbons on a gold substrate, which resolved the positions of individual atoms in the graphene nanoribbons. The team looked at more than 150 high-quality nanoribbons with different chiralities, all of which showed an unexpected feature, a regular raised border near their edges forming a hump or bevel. Once this was established as a real edge feature -- not the artifact of a folded ribbon or a flattened nanotube -- the chirality and electronic properties of well-ordered nanoribbon edges could be measured with confidence, and the edge regions theoretically modeled.

Electronics at the edge

"Two-dimensional graphene sheets are remarkable in how freely electrons move through them, including the fact that there's no band gap," Crommie says."Nanoribbons are different: electrons can become trapped in narrow channels along the nanoribbon edges. These edge-states are one-dimensional, but the electrons on one edge can still interact with the edge electrons on the other side, which causes an energy gap to open up."

Using an STM in spectroscopy mode (STS), the team measured electronic density changes as an STM tip was moved from a nanoribbon edge inward toward its interior. Nanoribbons of different widths were examined in this way. The researchers discovered that electrons are confined to the edge of the nanoribbons, and that these nanoribbon-edge electrons exhibit a pronounced splitting in their energy levels.

"In the quantum world, electrons can be described as waves in addition to being particles," Crommie notes. He says one way to picture how different edge states arise is to imagine an electron wave that fills the length of the ribbon and diffracts off the atoms near its edge. The diffraction patterns resemble water waves coming through slits in a barrier.

For nanoribbons with an armchair edge, the diffraction pattern spans the full width of the nanoribbon; the resulting electron states are quantized in energy and extend spatially throughout the entire nanoribbon. For nanoribbons with a zigzag edge, however, the situation is different. Here diffraction from edge atoms leads to destructive interference, causing the electron states to localize near the nanoribbon edges. Their amplitude is greatly reduced in the interior.

The energy of the electron, the width of the nanoribbon, and the chirality of its edges all naturally affect the nature and strength of these nanoribbon electronic states, an indication of the many ways the electronic properties of nanoribbons can be tuned and modified.

Says Crommie,"The optimist says, 'Wow, look at all the ways we can control these states -- this might allow a whole new technology!' The pessimist says, 'Uh-oh, look at all the things that can disturb a nanoribbon's behavior -- how are we ever going to achieve reproducibility on the atomic scale?'"

Crommie himself declares that"meeting this challenge is a big reason for why we do research. Nanoribbons have the potential to form exciting new electronic, magnetic, and optical devices at the nanoscale. We might imagine photovoltaic applications, where absorbed light leads to useful charge separation at nanoribbon edges. We might also imagine spintronics applications, where using a side-gate geometry would allow control of the spin polarization of electrons at a nanoribbon's edge."

Although getting there won't be simple --"The edges have to be controlled," Crommie emphasizes --"what we've shown is that it's possible to make nanoribbons with good edges and that they do, indeed, have characteristic edge states similar to what theorists had expected. This opens a whole new area of future research involving the control and characterization of graphene edges in different nanoscale geometries."

"Spatially resolving edge states of chiral graphene nanoribbons," by Chenggang Tao, Liying Jiao, Oleg V. Yazyev, Yen-Chia Chen, Juanjuan Feng, Xiaowei Zhang, Rodrigo B. Capaz, James M. Tour, Alex Zettle, Steven G. Louie, Hongjie Dai, and Michael F. Crommie, appears inNature Physicsand is available online athttp://www.nature.com/nphys/index.html. Funded at Berkeley Lab by DOE's Helios Energy Research Center, this collaborative project was supported jointly by the Office of Naval Research, the National Science Foundation, and the U.S. Department of Energy's Office of Science.

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High Temperature Milestone Achieved in Silicon Spintronics

The electron possesses an internal angular momentum called the spin. The International Technology Roadmap for Semiconductors has identified the electron's spin as a new state variable that should be explored as an alternative to the electron's charge for use beyond Moore's Law, a projection named after Intel co-founder Gordon E. Moore. Moore predicted in 1965 that the number of transistors per unit area in an integrated circuit would double approximately every two years as advances in fabrication technology enabled the devices to be made smaller. Although this approach has been remarkably successful, critical device dimensions now approach atomic length scales, so that further size scaling becomes untenable."Researchers have been forced to look beyond the simple reduction of size to develop future generations of electronic devices," states NRL senior scientist Dr. Berry Jonker."Electrical generation, manipulation and detection of significant spin polarization in silicon at temperatures that meet commercial and military requirements are essential to validate spin as an alternative to charge for a device technology beyond Moore's Law."

Using ferromagnetic metal / silicon dioxide contacts on silicon, NRL scientists Connie Li, Olaf van 't Erve and Jonker electrically generate and detect spin accumulation and precession in the silicon transport channel at temperatures up to 225°C, and conclude that the spin information can be transported in the silicon over distances readily compatible with existing fabrication technology. They thus overcome a major obstacle in achieving control of the spin variable at temperatures required for practical applications in the most widely utilized semiconductor.

To make a semiconductor spintronic device, one needs contacts that can both generate a current of spin-polarized electrons (called a spin injector), and detect the spin polarization of the electrons (spin detector) in the semiconductor. Because the magnetic contact interface is likely to introduce additional scattering and spin relaxation mechanisms not present in the silicon bulk, the region of the semiconductor directly beneath the contact is expected to be a critical factor in the development of any future spin technology. The NRL scientists probe the spin environment directly under the magnetic metal / silicon dioxide contact using the three terminal geometry illustrated in the accompanying

figure

. Demonstration of spin precession and dephasing in a magnetic field transverse to the injected spin orientation, known as the Hanle effect, is conclusive evidence of spin accumulation, and enables a direct measure of the spin lifetime, a critical parameter for device operation. The NRL researchers observed Hanle precession of the electron spin accumulation in the silicon channel under the contact for biases corresponding to both spin injection and extraction, and determine the corresponding spin lifetimes.

Electronic states can form at the contact interface and introduce deleterious effects for both charge and spin transport. These undesirable states can serve as traps which prevent propagation of either charge or spin in the silicon channel. In bulk silicon, the spin lifetime is known to depend upon the carrier density, and generally decreases as the electron density increases.."In this study we show that the spin lifetime determined from our measurements changes systematically as one changes carrier concentration of the particular silicon sample used," adds Jonker."Our results were obtained for a number of different carrier densities and show this trend, thus making it very clear that we obtain spin injection and accumulation in the silicon itself rather than in interface defect states." The result of this research rules out spin accumulation in interface states and demonstrates spin injection, accumulation and precession in the silicon channel.

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Transistors Reinvented Using New 3-D Structure

The three-dimensional Tri-Gate transistors represent a fundamental departure from the two-dimensional planar transistor structure that has powered not only all computers, mobile phones and consumer electronics to-date, but also the electronic controls within cars, spacecraft, household appliances, medical devices and virtually thousands of other everyday devices for decades.

"Intel's scientists and engineers have once again reinvented the transistor, this time utilizing the third dimension," said Intel President and CEO Paul Otellini."Amazing, world-shaping devices will be created from this capability as we advance Moore's Law into new realms."

Scientists have long recognized the benefits of a 3-D structure for sustaining the pace of Moore's Law as device dimensions become so small that physical laws become barriers to advancement. The key to this latest breakthrough is Intel's ability to deploy its novel 3-D Tri-Gate transistor design into high-volume manufacturing, ushering in the next era of Moore's Law and opening the door to a new generation of innovations across a broad spectrum of devices.

Moore's Law is a forecast for the pace of silicon technology development that states that roughly every 2 years transistor density will double, while increasing functionality and performance and decreasing costs. It has become the basic business model for the semiconductor industry for more than 40 years.

Unprecedented Power Savings and Performance Gains

Intel's 3-D Tri-Gate transistors enable chips to operate at lower voltage with lower leakage, providing an unprecedented combination of improved performance and energy efficiency compared to previous state-of-the-art transistors. The capabilities give chip designers the flexibility to choose transistors targeted for low power or high performance, depending on the application.

The 22nm 3-D Tri-Gate transistors provide up to 37 percent performance increase at low voltage versus Intel's 32nm planar transistors. This incredible gain means that they are ideal for use in small handheld devices, which operate using less energy to"switch" back and forth. Alternatively, the new transistors consume less than half the power when at the same performance as 2-D planar transistors on 32nm chips.

"The performance gains and power savings of Intel's unique 3-D Tri-Gate transistors are like nothing we've seen before," said Mark Bohr, Intel Senior Fellow."This milestone is going further than simply keeping up with Moore's Law. The low-voltage and low-power benefits far exceed what we typically see from one process generation to the next. It will give product designers the flexibility to make current devices smarter and wholly new ones possible. We believe this breakthrough will extend Intel's lead even further over the rest of the semiconductor industry."

Continuing the Pace of Innovation -- Moore's Law

Transistors continue to get smaller, cheaper and more energy efficient in accordance with Moore's Law -- named for Intel co-founder Gordon Moore. Because of this, Intel has been able to innovate and integrate, adding more features and computing cores to each chip, increasing performance, and decreasing manufacturing cost per transistor.

Sustaining the progress of Moore's Law becomes even more complex with the 22nm generation. Anticipating this, Intel research scientists in 2002 invented what they called a Tri-Gate transistor, named for the three sides of the gate. This announcement follows further years of development in Intel's highly coordinated research-development-manufacturing pipeline, and marks the implementation of this work for high-volume manufacturing.

The 3-D Tri-Gate transistors are a reinvention of the transistor. The traditional"flat" two-dimensional planar gate is replaced with an incredibly thin three-dimensional silicon fin that rises up vertically from the silicon substrate. Control of current is accomplished by implementing a gate on each of the three sides of the fin -- two on each side and one across the top -- rather than just one on top, as is the case with the 2-D planar transistor. The additional control enables as much transistor current flowing as possible when the transistor is in the"on" state (for performance), and as close to zero as possible when it is in the"off" state (to minimize power), and enables the transistor to switch very quickly between the two states (again, for performance).

Just as skyscrapers let urban planners optimize available space by building upward, Intel's 3-D Tri-Gate transistor structure provides a way to manage density. Since these fins are vertical in nature, transistors can be packed closer together, a critical component to the technological and economic benefits of Moore's Law. For future generations, designers also have the ability to continue growing the height of the fins to get even more performance and energy-efficiency gains.

"For years we have seen limits to how small transistors can get," said Moore."This change in the basic structure is a truly revolutionary approach, and one that should allow Moore's Law, and the historic pace of innovation, to continue."

World's First Demonstration of 22nm 3-D Tri-Gate Transistors

The 3-D Tri-Gate transistor will be implemented in the company's upcoming manufacturing process, called the 22nm node, in reference to the size of individual transistor features. More than 6 million 22nm Tri-Gate transistors could fit in the period at the end of this sentence.

Intel has demonstrated the world's first 22nm microprocessor, codenamed"Ivy Bridge," working in a laptop, server and desktop computer. Ivy Bridge-based Intel® Core™ family processors will be the first high-volume chips to use 3-D Tri-Gate transistors. Ivy Bridge is slated for high-volume production readiness by the end of this year.

This silicon technology breakthrough will also aid in the delivery of more highly integrated Intel® Atom™ processor-based products that scale the performance, functionality and software compatibility of Intel® architecture while meeting the overall power, cost and size requirements for a range of market segment needs.

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'Swiss Cheese' Design Enables Thin Film Silicon Solar Cells With Potential for Higher Efficiencies

One long-term option for low-cost, high-yield industrial production of solar panels from abundant raw materials can be found in amorphous silicon solar cells and microcrystalline silicon tandem cells (a.k.a. Micromorph) -- providing an energy payback within a year.

A drawback to these cells, however, is that the stable panel efficiency is less than the efficiency of presently dominate crystalline wafer-based silicon, explains Milan Vanecek, who heads the photovoltaic group at the Institute of Physics in Prague.

"To make amorphous and microcrystalline silicon cells more stable they're required to be very thin because of tight spacing between electrical contacts, and the resulting optical absorption isn't sufficient," he notes."They're basically planar devices. Amorphous silicon has a thickness of 200 to 300 nanometers, while microcrystalline silicon is thicker than 1 micrometer."

The team's new design focuses on optically thick cells that are strongly absorbing, while the distance between the electrodes remains very tight. They describe their design in the American Institute of Physics' journalApplied Physics Letters.

"Our new 3D design of solar cells relies on the mature, robust absorber deposition technology of plasma-enhanced chemical vapor deposition, which is a technology already used for amorphous silicon-based electronics produced for liquid crystal displays. We just added a new nanostructured substrate for the deposition of the solar cell," Vanecek says.

This nanostructured substrate consists of an array of zinc oxide (ZnO) nanocolumns or, alternatively, from a"Swiss cheese" honeycomb array of micro-holes or nano-holes etched into the transparent conductive oxide layer (ZnO).

"This latter approach proved successful for solar cell deposition," Vanecek elaborates."The potential of these efficiencies is estimated within the range of present multicrystalline wafer solar cells, which dominate solar cell industrial production. And the significantly lower cost of Micromorph panels, with the same panel efficiency as multicrystalline silicon panels (12 to 16 percent), could boost its industrial-scale production."

The next step is a further optimization to continue improving efficiency.

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3-D Terahertz Cloaking

Though this design can't translate into an invisibility cloak for the visible spectrum, it could have implications in diagnostics, security, and communication.

The cloak, designed by Cheng Sun, assistant professor of mechanical engineering at Northwestern's McCormick School of Engineering and Applied Science, uses microfabricated gradient-index materials to manipulate the reflection and refraction of light. Sun's results will be presented May 4 at CLEO: 2011, the annual Conference on Lasers and Electro-Optics.

Humans generally recognize objects through two features: their shape and color. To render an object invisible, one must be able to manipulate light so that it will neither scatter at an object's surface nor be absorbed or reflected by it (the process which gives objects color).

In order to manipulate light in the terahertz frequency, which lies between infrared and microwaves, Sun and his group developed metamaterials: materials that are designed at the atomic level. Sun's tiny, prism-shaped cloaking structure, less than 10 millimeters long, was created using a technique called electronic transfer microstereolithography, where researchers use a data projector to project an image on a liquid polymer, then use light to transform the liquid layer into a thin solid layer. Each of the prism's 220 layers has tiny holes that are much smaller than terahertz wavelengths, which means they can vary the refraction index of the light and render invisible anything located beneath a bump on the prism's bottom surface; the light then appears to be reflected by a flat surface.

Sun says the purpose of the cloak is not to hide items but to get a better understanding of how to design materials that can manipulate light propagation.

"This demonstrates that we have the freedom to design materials that can change the refraction index," Sun said."By doing this we can manipulate light propagation much more effectively."

The terahertz range has been historically ignored because the frequency is too high for electronics. But many organic compounds have a resonant frequency at the terahertz level, which means they could potentially be identified using a terahertz scanner. Sun's research into terahertz optics could have implications in biomedical research (safer detection of certain kinds of cancers) and security (using terahertz scanners at airports).

Next Sun hopes to use what he's learned through the cloak to create its opposite: a terahertz lens. He has no immediate plans to extend his invisibility cloak to visible frequencies.

"That is still far away," he said."We're focusing on one frequency range, and such a cloak would have to work across the entire spectrum."

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Improved Electrical Conductivity in Polymeric Composites

The researchers in Luxembourg, in cooperation with scientists from the Netherlands, have studied the electrical percolation of carbon nanotubes in a polymer matrix and shown the percolation threshold -- the point at which the polymer composite becomes conductive -- can be considerably lowered if small quantities of a conductive polymer latex are added. The simulations were done in Luxembourg, while the experiments took place at Eindhoven University.

"In this project, the idea is to use as little as possible carbon nanotubes and still benefit from their favourable properties," says the project leader at the University of Luxembourg, Prof. Tania Schilling,"we have discovered that, by adding a second component, we could make use of the resulting interactions to reach our goal." By mixing finely dispersed particles, so-called colloidal particles, of differing shapes and sizes in the medium, system-spanning networks form: the prerequisite for electrically conductive composites.

The recent finding of the materials scientists of the University of Luxembourg was published in the peer-reviewed, scientific journalNature Nanotechnology.This finding is a result of a cooperation of scientists at the University of Luxembourg, the Technische Universiteit Eindhoven and the Dutch Polymer Institute.

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New Material Could Improve Safety for First Responders to Chemical Hazards

In a recent issue of the journalAdvanced Materials, a team of researchers from the University of California, San Diego and Tyco Electronics describe how they made the carbon nanostructures and demonstrate their potential use as microsensors for volatile organic compounds.

First responders protect themselves from such vapors, whose composition is often unknown, by breathing through a canister filled with activated charcoal -- a gas mask. Airborne toxins stick to the carbon in the filter, trapping the dangerous materials.

As the filters become saturated, chemicals will begin to pass through. The respirator can then do more harm than good by providing an illusion of safety. But there is no easy way to determine when the filter is spent. Current safety protocols base the timing of filter changes on how long the user has worn the mask.

"The new sensors would provide a more accurate reading of how much material the carbon in the filters has actually absorbed," said team leader Michael Sailor, professor of chemistry and biochemistry and bioengineering at UC San Diego."Because these carbon nanofibers have the same chemical properties as the activated charcoal used in respirators, they have a similar ability to absorb organic pollutants."

Sailor's team assembled the nanofibers into repeating structures called photonic crystals that reflect specific wavelengths, or colors, of light. The wing scales of the Morpho butterfly, which give the insect its brilliant iridescent coloration, are natural examples of this kind of structure.

The sensors are an iridescent color too, rather than black like ordinary carbon. That color changes when the fibers absorb toxins -- a visible indication of their capacity for absorbing additional chemicals.

The agency that certifies respirators in the U.S., the National Institute of Occupational Safety and Health, has long sought such a sensor but the design requirements for a tiny, sensitive, inexpensive device that requires little power, have proved difficult to meet.

The materials that the team fabricated are very thin -- less than half the width of a human hair. Sailor's group has previously placed similar photonic sensors on the tips of optical fibers less than a millimeter across and shown that they can be inserted into respirator cartridges. And the crystals are sensitive enough to detect chemicals such as toluene at concentrations as low as one part per million.

Ting Gao, a senior researcher at the Polymers, Ceramics, and Technical Services Laboratories of Tyco Electronics in Menlo Park, California and Timothy L. Kelly, a NSERC post-doctoral fellow at UC San Diego co-authored the paper. The National Science Foundation, the Department of Homeland Security, the Natural Sciences and Engineering Research Council of Canada, and TYCO Electronics provided funding for the work.

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Chemist Designs New Polymer Structures for Use as 'Plastic Electronics'

Those tricks improve the properties of certain organic polymers that mimic the properties of traditional inorganic semiconductors and could make the polymers very useful in organic solar cells, light-emitting diodes and thin-film transistors.

Conductive polymers date back to the late 1970s when researchers Alan Heeger, Alan MacDiarmid and Hideki Shirakawa discovered that plastics, with certain arrangements of atoms, can conduct electricity. The three were awarded the 2000 Nobel Prize in Chemistry for the discovery.

Jeffries-EL, an Iowa State assistant professor of chemistry, is working with a post-doctoral researcher and nine doctoral students to move the field forward by studying the relationship between polymer structures and the electronic, physical and optical properties of the materials. They're also looking for ways to synthesize the polymers without the use of harsh acids and temperatures by making them soluble in organic solvents.

The building blocks of their work are a variety of benzobisazoles, molecules well suited for electrical applications because they efficiently transport electrons, are stable at high temperatures and can absorb photons.

And if the polymers are lacking in any of those properties, Jeffries-EL and her research group can do some chemical restructuring.

"With these polymers, if you don't have the properties you need, you can go back and change the wheel," Jeffries-EL said."You can change the chemical synthesis and produce what's missing."

That, she said, doesn't work with silicon and other inorganic materials for semiconductors:"Silicon is silicon. Elements are constant."

The National Science Foundation is supporting Jeffries-EL's polymer research with a five-year,$486,250 Faculty Early Career Development grant. She also has support from the Iowa Power Fund (a state program that supports energy innovation and independence) to apply organic semiconductor technology to solar cells.

The research group is seeing some results, including peer-reviewed papers over the past two years inPhysical Chemistry Chemical Physics, Macromolecules, the Journal of Polymer Science Part A: Polymer Chemistry,and theJournal of Organic Chemistry.

"This research is really about fundamental science," Jeffries-EL said."We're studying the relationships between structure and material properties. Once we have a polymer with a certain set of properties, what can we do?"

She and her research group are turning to the molecules for answers.

"In order to realize the full potential of these materials, they must be engineered at the molecular level, allowing for optimization of materials properties, leading to enhanced performance in a variety of applications," Jeffries-EL wrote in a research summary."As an organic chemist, my approach to materials begins with small molecules."

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Two Graphene Layers May Be Better Than One

Graphene, a single layer of carbon atoms, is prized for its remarkable properties, not the least of which is the way it conducts electrons at high speed. However, the lack of what physicists call a band gap -- an energetic threshold that makes it possible to turn a transistor on and off -- makes graphene ill-suited for digital electronic applications.

Researchers have known that bilayer graphene, consisting of two stacked graphene layers, acts more like a semiconductor when immersed in an electric field.

According to NIST researcher Nikolai Zhitenev, the band gap may also form on its own due to variations in the sheets' electrical potential caused by interactions among the graphene electrons or with the substrate (usually a nonconducting, or insulating material) that the graphene is placed upon.

NIST fellow Joseph Stroscio says that their measurements indicate that interactions with the disordered insulating substrate material causes pools of electrons and electron holes (basically, the absence of electrons) to form in the graphene layers. Both electron and hole"pools" are deeper on the bottom layer because it is closer to the substrate. This difference in"pool" depths, or charge density, between the layers creates the random pattern of alternating charges and the spatially varying band gap.

Manipulating the purity of the substrate could give researchers a way to finely control graphene's band gap and may eventually lead to the fabrication of graphene-based transistors that can be turned on and off like a semiconductor.

Still, as shown in the group's previous work, while these substrate interactions open the door to graphene's use as a practical electronic material, they lower the window on speed. Electrons do not move as well through substrate-mounted bilayer graphene; however, this may likely be compensated for by engineering the graphene/substrate interactions.

Stroscio's team plans to explore further the role that substrates may play in the creation and control of band gaps in graphene by using different substrate materials. If the substrate interactions can be reduced far enough, says Stroscio, the exotic quantum properties of bilayer graphene may be harnessed to create a new quantum field effect transistor.

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Exploring the Superconducting Transition in Ultra Thin Films

"Understanding exactly what happens when a normally insulating copper-oxide material transitions from the insulating to the superconducting state is one of the great mysteries of modern physics," said Brookhaven physicist Ivan Bozovic, lead author on the study.

One way to explore the transition is to apply an external electric field to increase or decrease the level of"doping" -- that is, the concentration of mobile electrons in the material -- and see how this affects the ability of the material to carry current. But to do this in copper-oxide (cuprate) superconductors, one needs extremely thin films of perfectly uniform composition -- and electric fields measuring more than 10 billion volts per meter. (For comparison, the electric field directly under a power transmission line is 10 thousand volts per meter.)

Bozovic's group has employed a technique called molecular beam epitaxy (MBE) to uniquely create such perfect superconducting thin films one atomic layer at a time, with precise control of each layer's thickness. Recently, they've shown that in such MBE-created films even a single cuprate layer can exhibit undiminished high-temperature superconductivity.

Now, they've applied the same technique to build ultrathin superconducting field effect devices that allow them to achieve the charge separation, and thus electric field strength, for these critical studies.

These devices are similar to the field-effect transistors (FETs) that are the basis of all modern electronics, in which a semiconducting material transports electrical current from the"source" electrode on one end of the device to a"drain" electrode on the other end. FETs are controlled by a third electrode, called a"gate," positioned above the source-drain channel -- separated by a thin insulator -- which switches the device on or off when a particular gate voltage is applied to it.

But because no known insulator could withstand the high fields required to induce superconductivity in the cuprates, the standard FET scheme doesn't work for high-temperature superconductor FETs. Instead, the scientists used electrolytes, liquids that conduct electricity, to separate the charges.

In this setup, when an external voltage is applied, the electrolyte's positively charged ions travel to the negative electrode and the negatively charged ions travel to the positive electrode. But when the ions reach the electrodes, they abruptly stop, as though they've hit a brick wall. The electrode"walls" carry an equal amount of opposite charge, and the electric field between these two oppositely charged layers can exceed the 10 billion volts per meter goal.

The result is a field effect device in which the critical temperature of a prototype high-temperature superconductor compound (lanthanum-strontium-copper-oxide) can be tuned by as much as 30 degrees Kelvin, which is about 80 percent of its maximal value -- almost ten times more than the previous record.

The scientists have now used this enhanced device to study some of the basic physics of high-temperature superconductivity.

One key finding: As the density of mobile charge carriers is increased, their cuprate film transitions from insulating to superconducting behavior when the film sheet resistance reaches 6.45 kilo-ohm. This is exactly equal to the Planck quantum constant divided by twice the electron charge squared -- h/(2e)². Both the Planck constant and electron charge are"atomic" units -- the minimum possible quantum of action and of electric charge, respectively, established after the advent of quantum mechanics early in the last century.

"It is striking to see a signature of such clearly quantum-mechanical behavior in a macroscopic sample (up to millimeter scale) and at a relatively high temperature," Bozovic said. Most people associate quantum mechanics with characteristic behavior of atoms and molecules.

This result also carries another surprising message. While it has been known for many years that electrons are paired in the superconducting state, the findings imply that they also form pairs (although localized and immobile) in the insulating state, unlike in any other known material. That sets the scientists on a more focused search for what gets these immobilized pairs moving when the transition to superconductivity occurs.

Superconducting FETs might also have direct practical applications. Semiconductor-based FETs are power-hungry, particularly when packed very densely to increase their speed. In contrast, superconductors operate with no resistance or energy loss. Here, the atomically thin layer construction is in fact advantageous -- it enhances the ability to control superconductivity using an external electric field.

"This is just the beginning," Bozovic said."We still have so much to learn about high-temperature superconductors. But as we continue to explore these mysteries, we are also striving to make ultrafast and power-saving superconducting electronics a reality."

This research was funded by the DOE Office of Science and the Swiss National Science Foundation.

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Functioning Synapse Created Using Carbon Nanotubes: Devices Might Be Used in Brain Prostheses or Synthetic Brains

The team, which was led by Professor Alice Parker and Professor Chongwu Zhou in the USC Viterbi School of Engineering Ming Hsieh Department of Electrical Engineering, used an interdisciplinary approach combining circuit design with nanotechnology to address the complex problem of capturing brain function.

In a paper published in the proceedings of the IEEE/NIH 2011 Life Science Systems and Applications Workshop in April 2011, the Viterbi team detailed how they were able to use carbon nanotubes to create a synapse.

Carbon nanotubes are molecular carbon structures that are extremely small, with a diameter a million times smaller than a pencil point. These nanotubes can be used in electronic circuits, acting as metallic conductors or semiconductors.

"This is a necessary first step in the process," said Parker, who began the looking at the possibility of developing a synthetic brain in 2006."We wanted to answer the question: Can you build a circuit that would act like a neuron? The next step is even more complex. How can we build structures out of these circuits that mimic the function of the brain, which has 100 billion neurons and 10,000 synapses per neuron?"

Parker emphasized that the actual development of a synthetic brain, or even a functional brain area is decades away, and she said the next hurdle for the research centers on reproducing brain plasticity in the circuits.

The human brain continually produces new neurons, makes new connections and adapts throughout life, and creating this process through analog circuits will be a monumental task, according to Parker.

She believes the ongoing research of understanding the process of human intelligence could have long-term implications for everything from developing prosthetic nanotechnology that would heal traumatic brain injuries to developing intelligent, safe cars that would protect drivers in bold new ways.

For Jonathan Joshi, a USC Viterbi Ph.D. student who is a co-author of the paper, the interdisciplinary approach to the problem was key to the initial progress. Joshi said that working with Zhou and his group of nanotechnology researchers provided the ideal dynamic of circuit technology and nanotechnology.

"The interdisciplinary approach is the only approach that will lead to a solution. We need more than one type of engineer working on this solution," said Joshi."We should constantly be in search of new technologies to solve this problem."

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Super-Small Transistor Created: Artificial Atom Powered by Single Electrons

The researchers report inNature Nanotechnologythat the transistor's central component -- an island only 1.5 nanometers in diameter -- operates with the addition of only one or two electrons. That capability would make the transistor important to a range of computational applications, from ultradense memories to quantum processors, powerful devices that promise to solve problems so complex that all of the world's computers working together for billions of years could not crack them.

In addition, the tiny central island could be used as an artificial atom for developing new classes of artificial electronic materials, such as exotic superconductors with properties not found in natural materials, explained lead researcher Jeremy Levy, a professor of physics and astronomy in Pitt's School of Arts and Sciences. Levy worked with lead author and Pitt physics and astronomy graduate student Guanglei Cheng, as well as with Pitt physics and astronomy researchers Feng Bi, Daniela Bogorin,and Cheng Cen. The Pitt researchers worked with a team from the University of Wisconsin at Madison led by materials science and engineering professor Chang-Beom Eom, including research associates Chung Wun Bark, Jae-Wan Park, and Chad Folkman. Also part of the team were Gilberto Medeiros-Ribeiro, of HP Labs, and Pablo F. Siles, a doctoral student at the State University of Campinas in Brazil.

Levy and his colleagues named their device SketchSET, or sketch-based single-electron transistor, after a technique developed in Levy's lab in 2008 that works like a microscopic Etch A Sketch^TM, the drawing toy that inspired the idea. Using the sharp conducting probe of an atomic force microscope, Levy can create such electronic devices as wires and transistors of nanometer dimensions at the interface of a crystal of strontium titanate and a 1.2 nanometer thick layer of lanthanum aluminate. The electronic devices can then be erased and the interface used anew.

The SketchSET -- which is the first single-electron transistor made entirely of oxide-based materials -- consists of an island formation that can house up to two electrons. The number of electrons on the island -- which can be only zero, one, or two -- results in distinct conductive properties. Wires extending from the transistor carry additional electrons across the island.

One virtue of a single-electron transistor is its extreme sensitivity to an electric charge, Levy explained. Another property of these oxide materials is ferroelectricity, which allows the transistor to act as a solid-state memory. The ferroelectric state can, in the absence of external power, control the number of electrons on the island, which in turn can be used to represent the 1 or 0 state of a memory element. A computer memory based on this property would be able to retain information even when the processor itself is powered down, Levy said. The ferroelectric state also is expected to be sensitive to small pressure changes at nanometer scales, making this device potentially useful as a nanoscale charge and force sensor.

The research inNature Nanotechnologyalso was supported in part by grants from the U.S. Defense Advanced Research Projects Agency (DARPA), the U.S. Army Research Office, the National Science Foundation, and the Fine Foundation.

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New Kid on the Plasmonic Block: Researchers Find Plasmonic Resonances in Semiconductor Nanocrystals

"We have demonstrated well-defined localized surface plasmon resonances arising from p-type carriers in vacancy-doped semiconductor quantum dots that should allow for plasmonic sensing and manipulation of solid-state processes in single nanocrystals," says Berkeley Lab director Paul Alivisatos, a nanochemistry authority who led this research."Our doped semiconductor quantum dots also open up the possibility of strongly coupling photonic and electronic properties, with implications for light harvesting, nonlinear optics, and quantum information processing."

Alivisatos is the corresponding author of a paper in the journalNature Materialstitled"Localized surface plasmon resonances arising from free carriers in doped quantum dots." Co-authoring the paper were Joseph Luther and Prashant Jain, along with Trevor Ewers.

The term"plasmonics" describes a phenomenon in which the confinement of light in dimensions smaller than the wavelength of photons in free space make it possible to match the different length-scales associated with photonics and electronics in a single nanoscale device. Scientists believe that through plasmonics it should be possible to design computer chip interconnects that are able to move much larger amounts of data much faster than today's chips. It should also be possible to create microscope lenses that can resolve nanoscale objects with visible light, a new generation of highly efficient light-emitting diodes, and supersensitive chemical and biological detectors. There is even evidence that plasmonic materials can be used to bend light around an object, thereby rendering that object invisible.

The plasmonic phenomenon was discovered in nanostructures at the interfaces between a noble metal, such as gold or silver, and a dielectric, such as air or glass. Directing an electromagnetic field at such an interface generates electronic surface waves that roll through the conduction electrons on a metal, like ripples spreading across the surface of a pond that has been plunked with a stone. Just as the energy in an electromagnetic field is carried in a quantized particle-like unit called a photon, the energy in such an electronic surface wave is carried in a quantized particle-like unit called a plasmon. The key to plasmonic properties is when the oscillation frequency between the plasmons and the incident photons matches, a phenomenon known as localized surface plasmon resonance (LSPR). Conventional scientific wisdom has held that LSPRs require a metal nanostructure , where the conduction electrons are not strongly attached to individual atoms or molecules. This has proved not to be the case as Prashant Jain, a member of the Alivisatos research group and one of the lead authors of the Nature Materials paper, explains.

"Our study represents a paradigm shift from metal nanoplasmonics as we've shown that, in principle, any nanostructure can exhibit LSPRs so long as the interface has an appreciable number of free charge carriers, either electrons or holes," Jain says."By demonstrating LSPRs in doped quantum dots, we've extended the range of candidate materials for plasmonics to include semiconductors, and we've also merged the field of plasmonic nanostructures, which exhibit tunable photonic properties, with the field of quantum dots, which exhibit tunable electronic properties."

Jain and his co-authors made their quantum dots from the semiconductor copper sulfide, a material that is known to support numerous copper-deficient stoichiometries. Initially, the copper sulfide nanocrystals were synthesized using a common hot injection method. While this yielded nanocrystals that were intrinsically self-doped with p-type charge carriers, there was no control over the amount of charge vacancies or carriers.

"We were able to overcome this limitation by using a room-temperature ion exchange method to synthesize the copper sulfide nanocrystals," Jain says."This freezes the nanocrystals into a relatively vacancy-free state, which we can then dope in a controlled manner using common chemical oxidants."

By introducing enough free electrical charge carriers via dopants and vacancies, Jain and his colleagues were able to achieve LSPRs in the near-infrared range of the electromagnetic spectrum. The extension of plasmonics to include semiconductors as well as metals offers a number of significant advantages, as Jain explains.

"Unlike a metal, the concentration of free charge carriers in a semiconductor can be actively controlled by doping, temperature, and/or phase transitions," he says."Therefore, the frequency and intensity of LSPRs in dopable quantum dots can be dynamically tuned. The LSPRs of a metal, on the other hand, once engineered through a choice of nanostructure parameters, such as shape and size, is permanently locked-in."

Jain envisions quantum dots as being integrated into a variety of future film and chip-based photonic devices that can be actively switched or controlled, and also being applied to such optical applications as in vivo imaging. In addition, the strong coupling that is possible between photonic and electronic modes in such doped quantum dots holds exciting potential for applications in solar photovoltaics and artificial photosynthesis

"In photovoltaic and artificial photosynthetic systems, light needs to be absorbed and channeled to generate energetic electrons and holes, which can then be used to make electricity or fuel," Jain says."To be efficient, it is highly desirable that such systems exhibit an enhanced interaction of light with excitons. This is what a doped quantum dot with an LSPR mode could achieve."

The potential for strongly coupled electronic and photonic modes in doped quantum dots arises from the fact that semiconductor quantum dots allow for quantized electronic excitations (excitons), while LSPRs serve to strongly localize or confine light of specific frequencies within the quantum dot. The result is an enhanced exciton-light interaction. Since the LSPR frequency can be controlled by changing the doping level, and excitons can be tuned by quantum confinement, it should be possible to engineer doped quantum dots for harvesting the richest frequencies of light in the solar spectrum.

Quantum dot plasmonics also hold intriguing possibilities for future quantum communication and computation devices.

"The use of single photons, in the form of quantized plasmons, would allow quantum systems to send information at nearly the speed of light, compared with the electron speed and resistance in classical systems," Jain says."Doped quantum dots by providing strongly coupled quantized excitons and LSPRs and within the same nanostructure could serve as a source of single plasmons."

Jain and others in Alivsatos' research group are now investigating the potential of doped quantum dots made from other semiconductors, such as copper selenide and germanium telluride, which also display tunable plasmonic or photonic resonances. Germanium telluride is of particular interest because it has phase change properties that are useful for memory storage devices.

"A long term goal is to generalize plasmonic phenomena to all doped quantum dots, whether heavily self-doped or extrinsically doped with relatively few impurities or vacancies," Jain says.

This research was supported by the DOE Office of Science.

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Collecting the Sun's Energy: Novel Electrode for Flexible Thin-Film Solar Cells

The scarcity of raw materials and increasing usage of rare metals is making electronic components and devices more and more costly. Such rare metals are used, for example, to make the transparent electrodes found in mobile phone touchscreen displays, liquid-crystal displays, organic LEDs and thin-film solar cells. The material of choice in these cases is indium tin oxide (ITO), a largely transparent mixed oxide. Because ITO is relatively expensive, however, it is uneconomic to use in large area applications such as solar cells.

The search for alternatives

Indium-free transparent oxides do exist, but with demand for them increasing they too are tending to become scarce. In addition, the principal disadvantages such as brittleness remain. The search for alternative coatings which are both transparent and electrically conductive is therefore intense, with materials such as conductive polymers, carbon nanotubes or graphenes coming under scrutiny. Carbon-based electrodes, however, generally show excessive surface resistance values which make them poor electrical conductors. If a metallic grid is integrated into the organic layer, it reduces not just its resistance but also its mechanical stability. If a solar cell made out of this material is bent, the electrode layers break and are no longer conductive. The challenge thus consists of manufacturing flexible yet stable conductive substrates, ideally in a cost-effective industrial rolling process.

One solution: woven electrodes

One particularly promising possibility is the use of a transparent flexible woven polymer, which Empa has developed together with the company Sefar AG in a project financially supported by the Swiss Commission for Technology and Innovation (CTI). Sefar, which specializes in precision fabrics, is able to produce the woven polymer economically and in large quantities using a roll to roll process similar to the way newspapers are printed. Metal wires woven into the material ensure that it is electrically conductive. In a second process step the material is embedded in an inert plastic layer which does not, however, completely cover the metal filaments, thus retaining its conductivity. The electrode which results is transparent, stable and yet flexible. The Empa researchers then applied a series of coatings to this new substrate to create a novel organic solar cell whose efficiency is compatible to conventional ITO-based cells. In addition, the woven electrode is significantly more stable when deformed than commercially available flexible plastic substrates to which a thin layer of conductive ITO has been applied.

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New Spin on Graphene Makes It Magnetic

The results, reported inScience, could be a potentially huge breakthrough in the field of spintronics.

Spintronics is a group of emerging technologies that exploit the intrinsic spin of the electron, in addition to its fundamental electric charge that is exploited in microelectronics.

Billions of spintronics devices such as sensors and memories are already being produced. Every hard disk drive has a magnetic sensor that uses a flow of spins, and magnetic random access memory (MRAM) chips are becoming increasingly popular.

The findings are part of a large international effort involving research groups from the US, Russia, Japan and the Netherlands.

The key feature for spintronics is to connect the electron spin to electric current as current can be manipulated by means routinely used in microelectronics.

It is believed that, in future spintronics devices and transistors, coupling between the current and spin will be direct, without using magnetic materials to inject spins as it is done at the moment.

So far, this route has only been demonstrated by using materials with so-called spin-orbit interaction, in which tiny magnetic fields created by nuclei affect the motion of electrons through a crystal. The effect is generally small which makes it difficult to use.

The researchers found a new way to interconnect spin and charge by applying a relatively weak magnetic field to graphene and found that this causes a flow of spins in the direction perpendicular to electric current, making a graphene sheet magnetised.

The effect resembles the one caused by spin-orbit interaction but is larger and can be tuned by varying the external magnetic field.

The Manchester researchers also show that graphene placed on boron nitride is an ideal material for spintronics because the induced magnetism extends over macroscopic distances from the current path without decay.

The team believes their discovery offers numerous opportunities for redesigning current spintronics devices and making new ones such as spin-based transistors.

Professor Geim said:"The holy grail of spintronics is the conversion of electricity into magnetism or vice versa.

"We offer a new mechanism, thanks to unique properties of graphene. I imagine that many venues of spintronics can benefit from this finding."

Antonio Castro Neto, a physics professor from Boston who wrote a news article for theSciencemagazine which accompanies the research paper commented:"Graphene is opening doors for many new technologies.

"Not surprisingly, the 2010 Nobel Physics prize was awarded to Andre Geim and Kostya Novoselov for their groundbreaking experiments in this material.

"Apparently not satisfied with what they have accomplished so far, Geim and his collaborators have now demonstrated another completely unexpected effect that involves quantum mechanics at ambient conditions. This discovery opens a new chapter to the short but rich history of graphene."

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First Non-Trivial Atom Circuit: Progress Toward an Atom SQUID

The newly published work was done at the Joint Quantum Institute, a NIST/UM collaboration.

Ultracold gases, such as the Bose-Einstein condensate of sodium atoms in this experiment, are fluids that exhibit the unusual rules of the quantum world. Atomic quantum fluids show promise for constructing ultraprecise versions of sensors and other devices such as gyroscopes (which stabilize objects and aid in navigation). Superfuid helium circuits have already been used to detect rotation. Superconducting quantum interference devices (SQUIDs) use superconducting electrons in a loop to make highly sensitive measurements of magnetic fields. Researchers are striving to create an ultracold-gas version of a SQUID, which could detect rotation. Combined with ultracold atomic-gas analogs of other electronic devices and circuits, or"atomtronics" that have been envisioned, such as diodes and transistors, this work could set the stage for a new generation of ultracold-gas-based precision sensors.

To make their atom circuit, researchers created a long-lived persistent current -- a frictionless flow of particles -- in a Bose-Einstein condensate of sodium atoms held by an arrangement of lasers in a so-called optical trap that confines them to a toroidal, or donut, shape. Persistent flow -- occurring for a record-high 40 seconds in this experiment -- is a hallmark of superfluidity, the fluid analog of superconductivity.

The atom current does not circle the ring at just any velocity, but only at specified values, corresponding in this experiment to just a single quantum of angular momentum. A focused laser beam creates the circuit element -- a barrier across one side of the ring. The barrier constitutes a tunable"weak link" that can turn off the current around the loop.

Superflow stops abruptly when the strength of the barrier is sufficiently high. Like water in a pinched garden hose, the atoms speed up in the vicinity of the barrier. But when the velocity reaches a critical value, the atoms encounter resistance to flow (viscosity) and the circulation stops, as there are no external forces to sustain it.

In atomic Bose-Einstein condensates, researchers have previously created Josephson junctions, a thin barrier separating two superfluid regions, in a single atomic trap. SQUIDs require a Josephson junction in a circuit. This present work represents the implementation of a complete atom circuit, containing a superfluid ring of current and a tunable weak link barrier. This is an important step toward realizing an atomic SQUID analog.

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New Research Advances Understanding of Lead Selenide Nanowires

Now, a research team at the University of Pennsylvania's schools of Engineering and Applied Science and Arts and Sciences has shown how to control the characteristics of semiconductor nanowires made of a promising material: lead selenide.

Led by Cherie Kagan, professor in the departments of Electrical and Systems Engineering, Materials Science and Engineering and Chemistry and co-director of Pennergy, Penn's center focused on developing alternative energy technologies, the team's research was primarily conducted by David Kim, a graduate student in the Materials Science and Engineering program.

The team's work was published online in the journalACS Nanoand will be featured in the Journal's April podcast.

The key contribution of the team's work has to do with controlling the conductive properties of lead selenide nanowires in circuitry. Semiconductors come in two types,nandp, referring to the negative or positive charge they can carry. The ones that move electrons, which have a negative charge, are called"n-type." Their"p-type" counterparts don't move protons but rather the absenceof an electron -- a"hole" -- which is the equivalent of moving a positive charge.

Before they are integrated into circuitry, the semiconductor nanowire must be"wired up" into a device. Metal electrodes must be placed on both ends to allow electricity to flow in and out; however, the"wiring" may influence the observed electrical characteristics of the nanowires, whether the device appears to ben-type orp-type. Contamination, even from air, can also influence the device type. Through rigorous air-free synthesis, purification and analysis, they kept the nanowires clean, allowing them to discover the unique properties of these lead selenide nanomaterials.

Researchers designed experiments allowing them to separate the influence of the metal"wiring" on the motion of electrons and holes from that of the behavior intrinsic to the lead selenide nanowires. By controlling the exposure of the semiconductor nanowire device to oxygen or the chemical hydrazine, they were able to change the conductive properties betweenp-type andn-type. Altering the duration and concentration of the exposure, the nanowire device type could be flipped back and forth.

"If you expose the surfaces of these structures, which are unique to nanoscale materials, you can make themp-type, you can make themn-type, and you can make them somewhere in between, where it can conduct both electrons and holes," Kagan said."This is what we call 'ambipolar.'"

Devices combining onen-type and onep-type semiconductor are used in many high-tech applications, ranging from the circuits of everyday electronics, to solar cells and thermoelectrics, which can convert heat into electricity.

"Thinking about how we can build these things and take advantage of the characteristics of nanoscale materials is really what this new understanding allows," Kagan said.

Figuring out the characteristics of nanoscale materials and their behavior in device structures are the first steps in looking forward to their applications.

These lead selenide nanowires are attractive because they may be synthesized by low-cost methods in large quantities.

"Compared to the big machinery you need to make other semiconductor devices, it's significantly cheaper," Kagan said."It doesn't look much more complicated than the hoods people would recognize from when they had to take chemistry lab."

In addition to the low cost, the manufacturing process for lead selenide nanowires is relatively easy and consistent.

"You don't have to go to high temperatures to get mass quantities of these high-quality lead selenide nanowires," Kim said."The techniques we use are high yield and high purity; we can use all of them."

And because the conductive qualities of the lead selenide nanowires can be changed while they are situated in a device, they have a wider range of functionality, unlike traditional silicon semiconductors, which must first be"doped" with other elements to make them"p" or"n."

The Penn team's work is a step toward integrating these nanomaterials in a range of electronic and optoelectronic devices, such as photo sensors.

The research was conducted by Kim and Kagan, along with Materials Science and Engineering undergraduate and graduate students Tarun R. Vemulkar and Soong Ju Oh; Weon-Kyu Koh, a graduate student in Chemistry; and Christopher B. Murray, a professor in Chemistry and in Materials Science and Engineering.

This work was supported with funding from the National Science Foundation Division of Materials Research, the National Science Foundation Solar Program and the National Science Foundation Nano-Bio Interface Center.

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Scientists Develop New Technology for Stroke Rehabilitation

In a paper to be presented this week (6 April) at the Institution of Engineering and Technology (IET) Assisted Living Conference, Dr Geoff Merrett, a lecturer in electronic systems and devices, will describe the design and evaluation of three technologies which could help people who are affected by stroke to regain movement in their hand and arm.

Dr Merrett worked with Dr Sara Demain, a lecturer in physiotherapy and Dr Cheryl Metcalf, a researcher in electronic systems and devices, to develop three 'tactile' devices which generate a realistic 'sense of touch' and sensation -- mimicking those involved in everyday activities.

Dr Demain says:"Most stroke rehabilitation systems ignore the role of sensation and they only allow people repetitive movement. Our aim is to develop technology which provides people with a sense of holding something or of feeling something, like, for example, holding a hot cup of tea, and we want to integrate this with improving motor function."

Three tactile devices were developed and tested on patients who had had a stroke and on healthy participants. The devices were: a 'vibration' tactile device, which users felt provided a good indication of touch but did not really feel as if they were holding anything; a 'motor-driven squeezer' device, which users said felt like they were holding something, a bit like catching a ball; and a 'shape memory alloy' device which has thermal properties and creates a sensation like picking up a cup of tea.

Dr Merrett adds:"We now have a number of technologies, which we can use to develop sensation. This technology can be used on its own as a stand-alone system to help with sensory rehabilitation or it could be used alongside existing health technologies such as rehabilitation robots or gaming technologies which help patient rehabilitation."

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Golden Window Electrodes Developed for Organic Solar Cells

This ultra-low thickness means that even at the current high gold price the cost of the gold needed to fabricate one square metre of this electrode is only around£4.5. It can also be readily recouped from the organic solar cell at the end of its life and since gold is already widely used to form reliable interconnects it is no stranger to the electronics industry.

Organic solar cells have long relied on Indium Tin Oxide (ITO) coated glass as the transparent electrode, although this is largely due to the absence of a suitable alternative. ITO is a complex, unstable material with a high surface roughness and tendency to crack upon bending if supported on a plastic substrate. If that wasn't bad enough one of its key components, indium, is in short supply making it relatively expensive to use.

An ultra-thin film of air-stable metal like gold would offer a viable alternative to ITO, but until now it has not proved possible to deposit a film thin enough to be transparent without being too fragile and electrically resistive to be useful.

Now research led by Dr Ross Hatton and Professor Tim Jones in the University of Warwick 's department of Chemistry has developed a rapid method for the preparation of robust, ultra-thin gold films on glass. Importantly this method can be scaled up for large area applications like solar cells and the resulting electrodes are chemically very well-defined.

Dr Hatton says"This new method of creating gold based transparent electrodes is potentially widely applicable for a variety of large area applications, particularly where stable, chemically well-defined, ultra-smooth platform electrodes are required, such as in organic optoelectronics and the emerging fields of nanoelectronics and nanophotonics."

The paper documents the team's success in creating this simple, practical and effective method of depositing the films onto glass, and also reports how the optical properties can be fine tuned by perforating the film with tiny circular holes using something as simple as polystyrene balls. The University of Warwick research team has also had some early success in depositing ultra-thin gold films directly on plastic substrates, an important step towards realising the holy grail of truly flexible solar cells. This innovation is set to be exploited by Molecular Solar Ltd, a Warwick spinout company dedicated to commercialising the discoveries of its academic founders in the area of organic solar cells.

This work was supported by the European Regional Development Fund (ERDF) / Advantage West Midlands Science City SCRA AM2 project, the Engineering and Physical Sciences Research Council (EPSRC) and the Royal Academy of Engineering.

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Replacing Batteries May Become a Thing of the Past, Thanks to 'Soft Generators'

A class of variable capacitor generators known as"dielectric elastomer generators" (DEGs) shows great potential for wearable energy harvesting. In fact, researchers at the Auckland Bioengineering Institute's Biomimetics Lab believe DEGs may enable light, soft, form-fitting, silent energy harvesters with excellent mechanical properties that match human muscle. They describe their findings in the American Institute of Physics' journalApplied Physics Letters.

"Imagine soft generators that produce energy by flexing and stretching as they ride ocean waves or sway in the breeze like a tree," says Thomas McKay, a Ph.D. candidate working on soft generator research at the Biomimetics Lab."We've developed a low-cost power generator with an unprecedented combination of softness, flexibility, and low mass. These characteristics provide an opportunity to harvest energy from environmental sources with much greater simplicity than previously possible."

Dielectric elastomers, often referred to as artificial muscles, are stretchy materials that are capable of producing energy when deformed. In the past, artificial muscle generators required bulky, rigid, and expensive external electronics.

"Our team eliminated the need for this external circuitry by integrating flexible electronics -- dielectric elastomer switches -- directly onto the artificial muscles themselves. One of the most exciting features of the generator is that it's so simple; it simply consists of rubber membranes and carbon grease mounted in a frame," McKay explains.

McKay and his colleagues at the Biomimetics Lab are working to create soft dexterous machines that comfortably interface with living creatures and nature in general. The soft generator is another step toward fully soft devices; it could potentially be unnoticeably incorporated into clothing and harvest electricity from human movement. When this happens, worrying about the battery powering your cell phone or other portable electronics dying on you will become a thing of the past. And as an added bonus, this should help keep batteries out of landfills.

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Self-Cooling Observed in Graphene Elctronics

Led by mechanical science and engineering professor William King and electrical and computer engineering professor Eric Pop, the team will publish its findings in the April 3 advance online edition of the journalNature Nanotechnology.

The speed and size of computer chips are limited by how much heat they dissipate. All electronics dissipate heat as a result of the electrons in the current colliding with the device material, a phenomenon called resistive heating. This heating outweighs other smaller thermoelectric effects that can locally cool a device. Computers with silicon chips use fans or flowing water to cool the transistors, a process that consumes much of the energy required to power a device.

Future computer chips made out of graphene -- carbon sheets 1 atom thick -- could be faster than silicon chips and operate at lower power. However, a thorough understanding of heat generation and distribution in graphene devices has eluded researchers because of the tiny dimensions involved.

The Illinois team used an atomic force microscope tip as a temperature probe to make the first nanometer-scale temperature measurements of a working graphene transistor. The measurements revealed surprising temperature phenomena at the points where the graphene transistor touches the metal connections. They found that thermoelectric cooling effects can be stronger at graphene contacts than resistive heating, actually lowering the temperature of the transistor.

"In silicon and most materials, the electronic heating is much larger than the self-cooling," King said."However, we found that in these graphene transistors, there are regions where the thermoelectric cooling can be larger than the resistive heating, which allows these devices to cool themselves. This self-cooling has not previously been seen for graphene devices."

This self-cooling effect means that graphene-based electronics could require little or no cooling, begetting an even greater energy efficiency and increasing graphene's attractiveness as a silicon replacement.

"Graphene electronics are still in their infancy; however, our measurements and simulations project that thermoelectric effects will become enhanced as graphene transistor technology and contacts improve" said Pop, who is also affiliated with the Beckman Institute for Advanced Science, and the Micro and Nanotechnology Laboratory at the U. of I.

Next, the researchers plan to use the AFM temperature probe to study heating and cooling in carbon nanotubes and other nanomaterials.

King also is affiliated with the department of materials science and engineering, the Frederick Seitz Materials Research Laboratory, the Beckman Institute, and the Micro and Nanotechnology Laboratory.

The Air Force Office of Scientific Research and the Office of Naval Research supported this work. Co-authors of the paper included graduate student Kyle Grosse, undergraduate Feifei Lian and postdoctoral researcher Myung-Ho Bae.

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A Measurement First: 'Noise Thermometry' System Measures Boltzmann Constant

The Boltzmann constant* relates energy to temperature for individual particles such as atoms. The accepted value of this constant is based mainly on a 1988 NIST measurement performed using acoustic gas thermometry, with a relative standard uncertainty of less than 2 parts per million (ppm). The technique is highly accurate but the experiment is complex and difficult to perform. To assure that the Boltzmann constant can be determined accurately around the world, scientists have been trying to develop different methods that can reproduce this value with comparable uncertainty.

The latest NIST experiment used an electronic technique called Johnson noise thermometry (JNT) to measure the Boltzmann constant with an uncertainty of 12 ppm. The results are consistent with the currently recommended value for this constant. NIST researchers aim to make additional JNT measurements with improved uncertainties of 5 ppm or less, a level of precision that would help update crucial underpinnings of science, including the definition of the Kelvin, the international unit of temperature.

The international metrology community is expected to soon fix the value of the Boltzmann constant, which would then redefine the Kelvin as part of a larger effort to link all units to fundamental constants. This approach would be the most stable and universal way to define measurement units, in contrast to traditional measurement unit standards based on physical objects or substances. The Kelvin is now defined in terms of the triple-point temperature of water (273.16 K, or about 0 degrees C and 32 degrees F), or the temperature and pressure at which water's solid, liquid and vapor forms coexist in balance. This value may vary slightly depending on chemical impurities.

The NIST JNT system measures very small electrical noise in resistors, a common electronic component, when they are cooled to the water triple point temperature. This"Johnson noise" is created by the random motion of electrons, and the signals they generate are directly proportional to temperature. The electronic devices measuring the noise power are calibrated with electrical signals synthesized by a superconducting voltage source based on fundamental principles of quantum mechanics. This unique feature enables the JNT system to match electrical power and thermal-noise power at the triple point of water, and assures that copies of the system will produce identical results. NIST researchers recently improved the apparatus to reduce the statistical uncertainty, systematic errors and electromagnetic interference. Additional improvements in the electronics are expected to further reduce measurement uncertainties.

The new measurements were made in collaboration with guest researchers from the Politecnico di Torino, Italy; the National Institute of Metrology, China; the University of Twente, The Netherlands; the National Metrology Institute of Japan, Tsukuba, Japan; and the Measurement Standards Laboratory, New Zealand.

* The currently accepted value of the Boltzmann Constant is 1.380 6504 x 10-23 joules/kelvin.

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Next-Generation Computers: Advance in Microchannel Manufacturing Opens New Industry Applications

This type of technology will be needed, researchers say, in next-generation computers, lasers, consumer electronics, automobile cooling systems, fuel processors, miniature heat pumps and more.

New industries and jobs are possible. A patent has been applied for, the findings reported in theJournal of Manufacturing Processes, and the university is seeking a partner for further commercial development.

"Even though microchannel arrays have enormous potential for more efficient heat transfer and chemical reactions, high production costs have so far held back the broad, mainstream use of the technology," said Brian Paul, a professor in the OSU School of Mechanical, Industrial and Manufacturing Engineering.

"In certain applications, this new approach has reduced material costs by 50 percent," Paul said."It could cut production bonding costs by more than 90 percent, compared to existing approaches to microchannel lamination. And the use of surface-mount adhesives is directly translatable to the electronics assembly industry, so there is less risk going to market.

"This type of manufacturing research could enable a microchannel revolution," he said.

Microchannels, the diameter of a human hair, can be patterned into the surface of a metal or plastic, and can be designed to speed up the heat exchange between fluids, or the mixing and separation of fluids during chemical reactions. The accelerated heat and mass transfer leads to smaller heat exchangers and chemical reactors and separators, such as a portable"home dialysis" system that evolved out of previous OSU research.

Cost and production issues, however, have until now constrained the wider industrial use of this technology. The new manufacturing technique developed at OSU should help change that.

"We have demonstrated the use of surface-mount adhesives to create microchannels on a wide variety of metals, including aluminum, which is very cheap," said Prawin Paulraj, an OSU doctoral candidate and lead author on the recent study."Bonding aluminum is difficult with conventional techniques."

These very thin pieces of patterned metal -- akin to aluminum foil -- can be bonded one on top of another to increase the number of microchannels in a heat exchanger, and the amount of fluid that can be processed. Creation of laminated microchannel arrays in a wide variety of materials is possible, including aluminum, copper, titanium, stainless steel and other metals.

"In computers and electronics, the heat generated by the electrical circuit is a limiting factor in how small you can make it," Paulraj said."Microchannel process technology provides an efficient way to cool computers and consumer electronics, and make them even smaller."

The adhesives are limited in temperature to about that of boiling water. The researchers say that possible uses might include radiators to cool an automobile engine or small, very efficient heat pumps for efficient air conditioning within buildings.

This research was conducted at the Microproducts Breakthrough Institute, a user facility of the Oregon Nanoscience and Microtechnologies Institute.

University officials are now seeking a commercial partner in private industry to continue development and marketing of the technology, according to Denis Sather, a licensing associate in the OSU Office for Commercialization and Corporate Development.

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Optical Transistor Advance: Physicists Rotate Beams of Light With Semiconductor

Light waves can oscillate in different directions -- much like a string that can vibrate up and down or left and right -- depending on the direction in which it is picked. This is called the polarization of light. Physicists at the Vienna University of Technology have now, together with researchers at Würzburg University, developed a method to control and manipulate the polarization of light using ultra thin layers of semiconductor material.

For future research on light and its polarization this is an important step forward -- and this breakthrough could even open up possibilities for completely new computer technology. The experiment can be viewed as the optical version of an electronic transistor. The results of the experiment have now been published in the journalPhysical Review Letters.

Controlling light with magnetic fields

The polarization of light can change, when it passes through a material in a strong magnetic field. This phenomenon is known as the"Faraday effect.""So far, however, this effect had only been observed in materials in which it was very weak," professor Andrei Pimenov explains. He carried out the experiments at the Institute for Solid State Physics of the TU Vienna, together with his assistant Alexey Shuvaev. Using light of the right wavelength and extremely clean semiconductors, scientists in Vienna and Würzburg could achieve a Faraday effect which is orders of magnitude stronger than ever measured before.

Now light waves can be rotated into arbitrary directions -- the direction of the polarization can be tuned with an external magnetic field. Surprisingly, an ultra-thin layer of less than a thousandth of a millimeter is enough to achieve this."Such thin layers made of other materials could only change the direction of polarization by a fraction of one degree," says professor Pimenov. If the beam of light is then sent through a polarization filter, which only allows light of a particular direction of polarization to pass, the scientists can, rotating the direction appropriately, decide whether the beam should pass or not.

The key to this astonishing effect lies in the behavior of the electrons in the semiconductor. The beam of light oscillates the electrons, and the magnetic field deflects their vibrating motion. This complicated motion of the electrons in turn affects the beam of light and changes its direction of polarization.

An optical transistor

In the experiment, a layer of the semiconductor mercury telluride was irradiated with light in the infrared spectral range."The light has a frequency in the terahertz domain -- those are the frequencies, future generations of computers may operate with," professor Pimenov believes."For years, the clock rates of computers have not really increased, because a domain has been reached, in which material properties just don't play along anymore." A possible solution is to complement electronic circuits with optical elements. In a transistor, the basic element of electronics, an electric current is controlled by an external signal. In the experiment at TU Vienna, a beam of light is controlled by an external magnetic field. The two systems are very much alike."We could call our system a light-transistor," Pimenov suggests.

Before optical circuits for computers can be considered, the newly discovered effect will prove useful as a tool for further research. In optics labs, it will play an important role in research on new materials and the physics of light.

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Novel Nanowires Boost Fuel Cell Efficiency

But one reason fuel cells aren't already more widespread is their lack of endurance. Over time, the catalysts used even in today's state-of-the-art fuels cells break down, inhibiting the chemical reaction that converts fuel into electricity. In addition, current technology relies on small particles coated with the catalyst; however, the particles' limited surface area means only a fraction of the catalyst is available at any given time.

Now a team of engineers at the Yale School of Engineering& Applied Science has created a new fuel cell catalyst system using nanowires made of a novel material that boosts long-term performance by 2.4 times compared to today's technology. Their findings appear on the cover of the April issue ofACS Nano.

Yale engineers Jan Schroers and André Taylor have developed miniscule nanowires made of an innovative metal alloy known as a bulk metallic glass (BMG) that have high surface areas, thereby exposing more of the catalyst. They also maintain their activity longer than traditional fuel cell catalyst systems.

Current fuel cell technology uses carbon black, an inexpensive and electrically conductive carbon material, as a support for platinum particles. The carbon transports electricity, while the platinum is the catalyst that drives the production of electricity. The more platinum particles the fuel is exposed to, the more electricity is produced. Yet carbon black is porous, so the platinum inside the inner pores may not be exposed. Carbon black also tends to corrode over time.

"In order to produce more efficient fuel cells, you want to increase the active surface area of the catalyst, and you want your catalyst to last," Taylor said.

At 13 nanometers in scale (about 1/10,000 the width of a human hair), the BMG nanowires that Schroers and Taylor developed are about three times smaller than carbon black particles. The nanowires' long, thin shape gives them much more active surface area per mass compared to carbon black. In addition, rather than sticking platinum particles onto a support material, the Yale team incorporated the platinum into the nanowire alloy itself, ensuring that it continues to react with the fuel over time.

It's the nanowires' unique chemical composition that makes it possible to shape them into such small rods using a hot-press method, said Schroers, who has developed other BMG alloys that can also be blow molded into complicated shapes. The BMG nanowires also conduct electricity better than carbon black and carbon nanotubes, and are less expensive to process.

So far Taylor has tested their catalyst system for alcohol-based fuel cells (including those that use ethanol and methanol as fuel sources), but they say the system could be used in other types of fuel cells and could one day be used in portable electronic devices such as laptop computers and cell phones as well as in remote sensors.

"This is the introduction of a new class of materials that can be used as electrocatalysts," Taylor said."It's a real step toward making fuel cells commercially viable and, ultimately, supplementing or replacing batteries in electronic devices."

Other authors of the paper include Marcelo Carmo, Ryan C. Sekol, Shiyan Ding and Golden Kumar (all of Yale University).

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